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Structures of (carbonato)bis(2,2'-bipyridine)cobalt(III) and (carbonato)bis(1,10-phenanthroline)cobalt(III) complexes

✍ Scribed by Niederhoffer, Eric C.; Martell, Arthur E.; Rudolf, Phil.; Clearfield, Abraham.

Book ID
120282119
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
991 KB
Volume
21
Category
Article
ISSN
0020-1669

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Bis(2,2′-bipyridine-κ2N,N′)(carbonato-κ2
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In the title compound, [Co(CO 3 )(C 10 H 8 N 2 ) 2 ](CF 3 SO 3 ), the Co III ion is coordinated by four N atoms from two chelating 2,2 0 -bipyridine ligands and two O atoms from a bidentate chelating carbonate anion, and has a distorted octahedral environment. C-HÁ Á ÁO hydrogen bonding is observed

Tris(O-isobutyl dithio­carbonato-κ2S,S′)
Tris(O-isobutyl dithio­carbonato-κ2S,S′)(1,10-phenanthroline)bis­muth(III)
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Single-crystal X-ray study T = 298 K Mean (C-C) = 0.015 A Disorder in main residue R factor = 0.045 wR factor = 0.119 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.