## Abstract The conformation and crystalline packing of Vβanhydrous amylose has been investigated by a combination of linked atom model building and Xβray diffraction analysis. The unit cell, the P2~1~2~1~2~1~ space group, the leftβhanded sixfold helical conformation with all O(6) in __gt__ rotatio
Structures of amylose subfractions with different molecular sizes
β Scribed by Yasuhito Takeda; Nobuhisa Maruta; Susumu Hizukuri
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 517 KB
- Volume
- 226
- Category
- Article
- ISSN
- 0008-6215
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β¦ Synopsis
The structures of subfractions (3&38% of the total), having G., -2500, -1500, and -400 (d.p., -6300, -1800, and -600), of amyloses from maize and rice have been analysed and found to be similar. The subfractions with d.p., -400 preponderated (66%) and were rich in linear molecules (maize 71%) rice 75%), whereas those with d.p., -2500 contained mainly branched molecules (maize 66%) rice 61%). The branched molecules in the subfractions with d.p., -2500 and -400 had large (maize 14.5, rice 10.5) and small (maize 3.1, rice 2.6) numbers of chains on average, respectively, and that in the subfraction withd$, -1500 had an intermediate number. The branched molecules in each subfraction comprised the short-chain fraction (probably G., -18), and the larger branched molecules had a larger number of the short chains. The C chain of the larger branched molecules appeared to be the longer.
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