The monoalkyl zinc radical, CHJn, may be observed by laser-induced fluorescence following UV photodissociation of ( CH3)2Zn. The fluorescence spectrum obtained upon excitation of the 08 and the 2: bands of the A-2 transition was assigned. A very simple fluorescence spectrum is obtained upon excitat
Structures and vibrational frequencies of the A′and A″ states of the CH3O radical
✍ Scribed by S.M. Colwell; R.D. Amos; N.C. Handy
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 581 KB
- Volume
- 109
- Category
- Article
- ISSN
- 0009-2614
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Structure and harmonic frequencies of ketenyl radical from UHF, MBPT( 2), CCSD and CCSD(T) calculations using DZP and TZ2P basis sets are presented. The equilibrium structure of the ground state is bent, while the linear structure represents a saddle point on the potential energy surface. The result
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Electronically excited OH (A 'C l , v=O) products were studied in the 210 to 290 nm photolysis of the reacting system CH, t 02+CH,02. The excitation spectrum is discussed in terms of formation of 0H(A22+, u=O) and OH(X %, u=O) from CH,O, and CH(X ZII) from CH+ Simplified systems of known reactions a