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Structures and lifetimes of 1,4-biradical intermediates in the photochemical cycloaddition reactions of N-benzoylindole with alkenes

โœ Scribed by Hastings, David J.; Weedon, Alan C.


Book ID
127041111
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
761 KB
Volume
56
Category
Article
ISSN
0022-3263

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The origin of the regioselectivity in th
โœ David J. Hastings; Alan C. Weedon ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 257 KB

Ultra-violet light irradiation of N-benzoylmdole, 1, m the presence of mono-substituted alkenes results in the formation of cyclobutane adducts of potential synthetic utility.2$3 The reaction is regioselectrve but not stereoselecttve, so that stereoisomers of adduct 3 are formed while 2 is either no