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Structure−Activity Relationship Study of the Metallocene Catalyst Activity in Ethylene Polymerization

✍ Scribed by Cruz, Victor L.; Ramos, Javier; Martinez, Sonia; Muñoz-Escalona, Antonio; Martinez-Salazar, Javier


Book ID
115505512
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
315 KB
Volume
24
Category
Article
ISSN
0276-7333

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X-ray photoelectron spectroscopy (XPS) has been applied to the study of a series of metaliocene catalysts, containing Zr, Ti or Hf. for the polymerization of ethylene. Surface atomic compositions, binding energies and valence band (VB) spectra have been measured. Surface compositions were found to b