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The influence of the metal net charge of non-metallocene early transition metal catalyst on the ethylene polymerization activity

✍ Scribed by Wu, ChunHong ;Li, HuaYi ;Feng, YuQi ;Hu, YouLiang

Book ID
107368597
Publisher
Elsevier
Year
2008
Tongue
English
Weight
426 KB
Volume
53
Category
Article
ISSN
2095-9273

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The influence of the transition metal an
The influence of the transition metal and the heteroatomic-bridge on the action of metallocene/methyl aluminoxane catalysts in ethylene polymerization and on the properties of the polymer
✍ Raul Quijada; Jairton Dupont; Dione CorrΓͺa Silveira; MΓ‘rcia S. Lacerda Miranda; πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 277 KB

This work reports a comparative study of the catalytic behaviour for a series of metallocenes derived from Ti, Zr, Hf and Nb, which after activation with methylaluminoxane can polymerize ethylene. Results show that the Zr metallocene with a -(CH3)2Si-bridge presents the highest activity, and the met