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Structure of μ-pyrazine-bis[(diethylenetriamine-N,N',N'')(diperchlorato-O)copper(II)]

✍ Scribed by Xu, D. ;Chen, C. ;Xu, Y. ;Cheng, C. ;Chen, J. ;Tang, W.


Book ID
114507711
Publisher
International Union of Crystallography
Year
1991
Tongue
English
Weight
436 KB
Volume
47
Category
Article
ISSN
0108-2701

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In the title compound, [Cu(C~4~H~13~N~3~)~2~](C~10~H~9~N~4~O~2~S)~2~, the Cu atom (site symmetry \overline{1}) displays a Jahn–Teller distorted octahedral CuN~6~ geometry arising from the two tridentate diethylenetriamine ligands. The cation and anion interact by way of N—H...N and N—H...O hydrogen