Structure of μ-pyrazine-bis[(diethylenetriamine-N,N',N'')(diperchlorato-O)copper(II)]
✍ Scribed by Xu, D. ;Chen, C. ;Xu, Y. ;Cheng, C. ;Chen, J. ;Tang, W.
- Book ID
- 114507711
- Publisher
- International Union of Crystallography
- Year
- 1991
- Tongue
- English
- Weight
- 436 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.040 A Ê R factor = 0.059 wR factor = 0.171 Data-to-parameter ratio = 23.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [Cu(C~4~H~13~N~3~)~2~](C~10~H~9~N~4~O~2~S)~2~, the Cu atom (site symmetry \overline{1}) displays a Jahn–Teller distorted octahedral CuN~6~ geometry arising from the two tridentate diethylenetriamine ligands. The cation and anion interact by way of N—H...N and N—H...O hydrogen