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Bis(diethyl­enetriamine-κ3N)copper(II) bis­(sulfadiazinate)

✍ Scribed by Hossain, G. M. Golzar ;Amoroso, A. J.


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
310 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, Cu(C~4~H~13~N~3~)~2~~2~, the Cu atom (site symmetry \overline{1}) displays a Jahn–Teller distorted octahedral CuN~6~ geometry arising from the two tridentate diethylenetriamine ligands. The cation and anion interact by way of N—H...N and N—H...O hydrogen bonds.


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Bis(1H-imidazole-κN3)­bis(3-methyl­benzo
✍ Xu, Tu-Gen ;Liu, Jia-Geng ;Xu, Duan-Jun 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 301 KB

In the title complex, [Cu(C 8 H 7 O 2 ) 2 (C 3 H 4 N 2 ) 2 ], the Cu II atom, located on an inversion center, has a square-planar coordination geometry formed by imidazole molecules and 3methylbenzoate anions. Hydrogen-bonding and C-HÁ Á Á interactions occur between imidazole and methylbenzoate liga