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Structure of μ-oxo-bis[trichloro(2,2-diisobutyl-1,3-dimethoxypropane-O,O')titanium(IV)]

✍ Scribed by Iiskola, E. ;Pelkonen, A. ;Kakkonen, H. J. ;Ahlgrén, M. ;Pakkanen, T. A. ;Pursiainen, J.


Book ID
114510194
Publisher
International Union of Crystallography
Year
1993
Tongue
English
Weight
356 KB
Volume
49
Category
Article
ISSN
0108-2701

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μ-2,2′-Biphenolato-κ2O:O′-μ-oxido-κ2O:O-
✍ Kuhn, Annemarie ;Muller, Alfred ;Conradie, Jeanet 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 198 KB

The coordination of [Ti(hfaa)~2~Cl~2~] (hfaa = hexafluoroacetylacetonate) with the hydroxyl-containing bidentate ligand 2,2′-biphenol yielded the title compound, [{Ti(hfaa)~2~}~2~(μ-2,2′-biphenolato)(μ-oxo)] or [Ti~2~(C~5~HF~6~O~2~)~4~(C~12~H~8~O~2~)O]. The molecule has crystallographic twofold rota