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Structure of Yellow Metal-Free and Yellow Cobalt-Containing Corrinoids

✍ Scribed by Dr. Gerhard Schlingmann; Dr. Bernd Dresow; Dr. Volker B. Koppenhagen; Dipl.-Chem. Wulf Becker; Dr. William S. Sherldrick

Publisher: John Wiley and Sons
Year: 1980
Tongue: English
Weight: 225 KB
Volume: 19
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.198003212

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## Abstract The η^4^‐diphosphacyclobutadiene complexes [M(η^5^‐C~5~R~5~)(η^4^‐P~2~C~2~Bu)] (M  Co, Rh; R  H, Me), react with Rh(I), Pt(O), and Pt(II) centers via the phosphorus lone paris of the rings of afford mixed metal complexes. The crystal and molecular structure of the novel hexarhodium co