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Structure of Tricarbonyl(diene)iron Complexes in Solution. Variable-Temperature Circular Dichroism of trans-μ-(2,3,5,6-Tetramethylidenebicyclo[2.2.2]octane)bis(tricarbonyliron) Complexes

✍ Scribed by Raphy Gabioud; Pierre Vogel


Book ID
102256116
Publisher
John Wiley and Sons
Year
1986
Tongue
German
Weight
461 KB
Volume
69
Category
Article
ISSN
0018-019X

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✦ Synopsis


Evionnaz

' ) The terms syn and anti are used to characterize the H-atoms oriented towards and away from the Fe(C0)3 moiety, respectively.


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305 35. Stereoselective Double Friedel-Crafts Acylation of trans-p -(2,3,6,7-Tetramethylidenebicyclo[3.2.l~octane)bis(tricarbonyIiron).

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✍ Enrico Tagliaferri; Philippe Campiche; Raymond Roulet; Raphy Gabioud; Pierre Vog 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 German ⚖ 559 KB

## Abstract The __Friedel__‐__Crafts__ monoacylation of __trans__‐η‐[(1__RS__,2__RS__,4__SR__,5__SR__,6__RS__,7__SR__,8__SR__)‐__C__,5,6,__C__‐η:__C__,7,8,__C__‐η‐(5,6,7,8‐tetramethylidene‐2‐bicyclo[2.2.2]octyl acetate)]‐bis(tricarbonyliron) ((±)‐**5**) is highly stereoselective and yields __trans_