Structure of tricarbonyl[1–6-η-(2-ethylanisole)]chromium
✍ Scribed by Baert, F. ;Lamiot, J. ;Lebibi, J. ;Brocard, J.
- Book ID
- 114505527
- Publisher
- International Union of Crystallography
- Year
- 1988
- Tongue
- English
- Weight
- 298 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0108-2701
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In the 2H-chromene series, complexation of the aromatic ring with chromium tricarbonyl, under thermal conditions, is totally regioselective even when aromatic substituents are introduced on the pyran ring. The complexation stabilizes the open form of these photochromic compounds and reduces the ther
## Abstract The Cr(CO)~3~‐complexed η6‐phenylpropargylic alcohols 3 react in a displacement rearrangement with thionyl chloride or chlorodiphenylphosphane to give the chloro‐ or phosphoryl allenyl substituted η6‐phenyl complexes 4 and 6, respectively. In the X‐ray crystal structure of the novel org