Structure of trans-dichlorobis[1,2-bis(diphenylphosphino)ethane]osmium(II) dichloromethane solvate
✍ Scribed by Levason, W. ;Champness, N. R. ;Webster, M.
- Book ID
- 114510352
- Publisher
- International Union of Crystallography
- Year
- 1993
- Tongue
- English
- Weight
- 208 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0108-2701
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In the title compound, [PtI~2~(C~26~H~24~P~2~)]·2CH~2~Cl~2~, the PtI~2~(dppe) [dppe = 1,2-bis(diphenylphosphino)ethane] molecules possess twofold rotation symmetry. The Pt coordination displays a square-planar arrangement, with the sum of the angles around the Pt atom being 360.01 (2)°. The Pt—I dis
Acta Cryst. (2001). E57, m433±m434 slightly longer in the THF adduct than the corresponding distances in the CH 2 Cl 2 adduct [2.141 (1) and 2.156 (1) A Ê ], but both NiÐBr bonds are very similar. In this structure, there is a stacking interaction between the THF ring and the C121Ð C126 phenyl ring,