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Structure of thiotropocin, a new sulfur-containing 7-membered antibiotic

✍ Scribed by Shigetoshi Tsubotani; Yoshikazu Wada; Kazuhide Kamiya; Hisayoshi Okazaki; Setsuo Harada

Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
211 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis

The structure of a new antibiotic thiotropocin is described. In the course of our antibiotic screening, a new antibiotic has been isolated as crystals by ethyl acetate extraction and silica gel chromatography from the fermentation broth of Pseudomonas sp. CB-104. The acidic lipophilic antibiotic has broad antibacterial spectra. This paper deals with the structural elucidation of the antibiotic, thiotropocin CL), named from its novel skeleton in combination with tropothione and oxathiole. The physico-chemical data of k are as follows; orange fine needles, mp 222-225'C(dec.),

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