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Structure of the products from the reaction of 4-phenyl-3H-1,2,4-triazole-3,5(4H)-dione with alcohols

✍ Scribed by Mackay, Donald; Taylor, Nicholas J.; Wigle, Ian D.


Book ID
126947041
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
427 KB
Volume
52
Category
Article
ISSN
0022-3263

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Cycloaddition Reactions of 7-Benzylidene
✍ Philip Clements; George E. Gream; Paul K. Kirkbride; Simon M. Pyke 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 German ⚖ 328 KB

## Abstract An (__E__)/(__Z)__ mixture (3 : 2) of 7‐benzylidenecycloocta‐1,3,5‐triene (**5**) is obtained when 1‐benzylcycloocta‐1,3,5,7‐tetraene (**7**), prepared by an improved procedure, is treated with __t__‐BuOK in THF. Alternatively, a __ca.__ 9 : 1 mixture (__E__)/(__Z__)‐**5** can be prepar