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Reaction of diazoalkanes with 4-substituted 1,2,4-triazole-3,5(4H)-diones

✍ Scribed by Izydore, Robert A.; Chapman, John J.; Mitchell, John A.; Cummings, Robert; Jones, George T.; Mclver, Christopher D.


Book ID
120052957
Publisher
Royal Society of Chemistry
Year
1988
Tongue
English
Weight
1007 KB
Volume
8
Category
Article
ISSN
1472-779X

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Cycloaddition Reactions of 7-Benzylidene
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## Abstract An (__E__)/(__Z)__ mixture (3 : 2) of 7‐benzylidenecycloocta‐1,3,5‐triene (**5**) is obtained when 1‐benzylcycloocta‐1,3,5,7‐tetraene (**7**), prepared by an improved procedure, is treated with __t__‐BuOK in THF. Alternatively, a __ca.__ 9 : 1 mixture (__E__)/(__Z__)‐**5** can be prepar