Structure of the polytypic β-form of P3N3(OCH2CF2CF2CH2O)F4
✍ Scribed by Wang, Z. ;Willett, R. D. ;Elias, A. J. ;Kirchmeier, R. L. ;Shreeve, J. M.
- Book ID
- 114515198
- Publisher
- International Union of Crystallography
- Year
- 1996
- Tongue
- English
- Weight
- 812 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0108-7681
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## Abstract Rate constants were determined for the reactions of OH radicals with the hydrofluoroethers (HFEs) CH~2~FCF~2~OCHF~2~(__k__~1~), CHF~2~CF~2~OCH~2~CF~3~ (__k__~2~), CF~3~CHFCF~2~OCH~2~CF~3~(__k__~3~), and CF~3~CHFCF~2~OCH~2~CF~2~CHF~2~(__k__~4~) by using a relative rate method. OH radical
## Abstract The intermolecular interaction energy curves of CH~3~OCH~3~CH~2~F~2~, CF~3~OCH~3~CH~2~F~2~, CF~3~OCF~3~CH~2~F~2~, CH~3~OCH~3~CHF~3~, CF~3~OCH~3~CHF~3~, and CF~3~OCF~3~CHF~3~ complexes were calculated by the MP2 level __ab initio__ molecular orbital method using the 6‐311G\*\* basi
A variety of relative and absolute techniques have been used to measure the reactivity of fluorine atoms with a series of halogenated organic compounds and CO. The following rate constants were derived, in units of cm3 molecule-' s-l: CH3F, (3.7 2 0.8) X CH3C1, (3.3 2 0.71 X 10 -'I; CH3Br, (3.0 2 0.