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Structure of the oxidative dimerization product of 4,6-di(tert-butyl)pyrogallol

โœ Scribed by V. V. Tkachev; S. M. Aldoshin; G. V. Shilov; V. N. Komissarov; Yu. A. Sayapin; M. S. Korobov; G. S. Borodkin; V. I. Minkin

Publisher
Springer
Year
2007
Tongue
English
Weight
368 KB
Volume
56
Category
Article
ISSN
1573-9171

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Structures of Oxidation Products of 4,6-Di-tert-butylpyrogallol. -The oxidation of title compound (I) with 1,4-benzoquinone affords the dimeric product (II) derived from a regio-and stereospecific dimerization of intermediate 1,2-benzoquinone (III), the expected oxidation product, according to a [4