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ChemInform Abstract: Structures of Oxidation Products of 4,6-Di-tert-butylpyrogallol.

✍ Scribed by A. I. Shif; S. N. Lyubchenko; O. Ya. Borbulevych; O. V. Shishkin; K. A. Lyssenko; L. P. Olekhnovich

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Structures of Oxidation Products of 4,6-Di-tert-butylpyrogallol.

-The oxidation of title compound (I) with 1,4-benzoquinone affords the dimeric product (II) derived from a regio-and stereospecific dimerization of intermediate 1,2-benzoquinone (III), the expected oxidation product, according to a [4+2] cycloaddition mechanism. The oxidation of (I) with potassium ferricyanide affords the dimer (IV) via a radical recombination mechanism. The structures of the oxidation products are confirmed by X-ray diffraction analyses. (Yields are given in g). -(SHIF, A.

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