The O-specific polysaccharide of the lipopolysaccharide from H. alvei strain 38 has been established by NMR spectroscopy (13C and 1H) and methylation analysis to have the repeating unit-->4)-beta-D-ManpNAc-(1-->4)-alpha-D-GlcpNAc(1-->.
Structure of the O-specific polysaccharide, containing a glycerol phosphate substituent, of Hafnia alvei strain 1220 lipopolysaccharide
✍ Scribed by Ursula Dabrowski; Janusz Dabrowski; Ewa Katzenellenbogen; Maria Bogulska; Elżbieta Romanowska
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 470 KB
- Volume
- 287
- Category
- Article
- ISSN
- 0008-6215
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✦ Synopsis
The O-specific polysaccharide of the lipopolysaccharide produced by Hafnia alvei strain 1220 contained D-glucose, D-galactose, N-acetyl-D-glucosamine, N-acetyl-L-fucosamine (2-acetamido-2,6-dideoxy-L-galactose), glycerol, and phosphate. It was proved by composition and methylation analyses, Smith degradation, dephosphorylation, and one- and two-dimensional 1H NMR spectroscopy to be a teichoic acid-like polymer with a branched hexasaccharide repeating unit of the following structure. [sequence: see text]
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