𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Structure of the O-specific polysaccharide chain of Shigella boydii type 5 lipopolysaccharide: a repeated study

✍ Scribed by Vyacheslav L. L'vov; Aleksander S. Shashkov; Yuriy A. Knirel; Aleksandra E. Arifulina; Sof'ya N. Senchenkova; Aleksander V. Yakovlev; Boris A. Dmitriev

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
628 KB
Volume
279
Category
Article
ISSN
0008-6215

No coin nor oath required. For personal study only.

✦ Synopsis

An acidic, partially O-acetylated O-specific polysaccharide was obtained by mild acid degradation of Shigella boydii type 5 lipopolysaccharide and studied by 1H and 13C NMR spectroscopy, including 2D COSY, 13C-1H heteronuclear COSY, 1D NOE, and 2D ROESY experiments, and chemical methods (sugar and methylation analysis, O-deacetylation, carboxyl reduction, solvolysis with anhydrous HF, partial acid hydrolysis. Smith degradation). It was concluded that the polysaccharide has a hexasaccharide repeating unit of the following structure: [Formula: See Text] with the degree of O-acetylation varying over 30-50%. The established structure differs from that proposed recently for the O-specific polysaccharide of the same S. boydii serotype [M.J. Albert et al., Carbohydr. Res., 265 (1994) 121-127].

πŸ“œ SIMILAR VOLUMES

Structural studies of the Shigella boydi
Structural studies of the Shigella boydii type 5 O-antigen polysaccharide
✍ M.John Alberta; Tord Holme; Bengt Lindberg; Johan Lindberg; M. Mosihuzzaman; Fir πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 488 KB

The structure of the Shigella boydii type 5 O-antigen polysaccharide has been investigated by sugar and methylation analyses, and specific degradations. It is proposed that it is composed of hexasaccharide repeating units with the following structure. The repeating unit also contains an O-acetyl gr

Structure of the O-specific polysacchari
Structure of the O-specific polysaccharide chain of Citrobacter freundii O28,1c lipopolysaccharide
✍ Nina A. Kocharova; Yuriy A. Knirel; Elena V. Kholodkova; Evgeny S. Stanislavsky πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 219 KB

NMR 0-Specific polysaccharide chains of lipopolysaccharides of a number of serotypes of an enterobacterium, Citrobacter freundii, have been structurally elucidated [l-3]. We now report the structure of a new 0-specific polysaccharide isolated from C. jkuzdii 028,lc.

The structure of the O-specific polysacc
The structure of the O-specific polysaccharide chain from Citrobacter O23-lipopolysaccharide
✍ Ewa Katzenellenbogen; Irena Ekiel; Elzbieta Romanowska πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 English βš– 526 KB

The structure of Citrobacter O23-specific polysaccharide has been shown by sugar and methylation analyses of the native and chemically degraded polysaccharide and by 1H- and 13C-n.m.r. spectroscopy to consist of the tetrasaccharide repeating-units: ----4)-alpha-D-Man-(1----2)-alpha-D-Man-(1----2)-be

Structure of the O-specific polysacchari
Structure of the O-specific polysaccharide chain of the lipopolysaccharide of Enterobacter agglomerans
✍ Yannis Karamanos; Ossarath Kol; Jean-Michel Wieruszeski; GΓ©rard Strecker; Bernar πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 514 KB

The O-specific polysaccharide isolated from the lipopolysaccharide of Enterobacter agglomerans was found, by methylation analysis, periodate oxidation, oxidative deamination, and NMR spectroscopy, to

Structural studies of O-specific polysac
Structural studies of O-specific polysaccharide chains of the lipopolysaccharide from Yersinia enterocolitica serovar O:10
✍ Raisa P. Gorshkova; Vladimir V. Isakov; Elena N. Kalmykova; Yury S. Ovodov πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 374 KB

Lipopolysaccharide (LPS) was isolated from Yersinia enterocolitica serovars O : 10 and O : 10 KL and the structural pattern of O-specific sugar chains elucidated. The rhamnan and L-xylulose (L-threo-pent-2-ulose) as constituents of the O-specific polysaccharide were obtained by autohydrolysis of the