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Structure of some α-aminomethylation products of nitramines

✍ Scribed by S. N. Shvedova; V. G. Avakyan; N. O. Cherskaya; T. A. Arestova; V. A. Shlyapochnikov; S. S. Novikov

Book ID
112439916
Publisher
Springer
Year
1973
Tongue
English
Weight
286 KB
Volume
22
Category
Article
ISSN
1573-9171

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✍ C.Peter Lillya; Thomas P. Sassi 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 144 KB

Fluoride-induced desilylation of a trimethylsilylcyclopropyl nitramine generated the first known nitramine a-anion, which was trapped in situ by electrophiles (H20, D20, and CH3CHO). In contrast, a trimethylsilylmethyl nitramine gave a product resulting from elimination of the elements of trimethyls