Keywards: cacspitenone, africanetype sesquiterpene, liverwon, Porellu cacspitans var. serigera Porella swurtziana Absrmet:. Caespitenone. previously isolated from the liverwort P. caespitans, has also been found in the close species P. smarrziana collected in Colombia and its st~ctmt revised to have
Structure of secoswartzianins A and B isolated from the liverwort Porella swartziana
β Scribed by Motoo Tori; Katsuyuki Nakashima; Tomoko Takeda; Yoshinori Asakawa
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- French
- Weight
- 163 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Absbue. Secoswartxianins A and B. have been found in P. swarfzia~ collected in Colombig and their armmes dtmmimd to be 3.4-secoafrimt aesquitapenes based on the extensive 2D NMR analyses and chemical mm.
We have been investigating the chemical constituents of liverworts from those collected not only in Japan but also all over the world'. We have encountered the chance to collect the liverwort Porella warrzima in Colombia and started a study on the constituents of this species to isolate a ram a-pyrone type compound,
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The liverwort Porella vernicosa Lindb. was cultured in vitro in Murashige and Skoog's medium. The pungent sesquiterpene dialdehyde, polygodial, was found as the major metabolite (20.3%). The second major metabolite was norpinguisone methyl ester (18.7%). In addition B -bisabolene (12.7%), drimenol (
Total Synthesis and Absolute Configuration of Riccardiphenols A and B, Isolated from the Liverwort Riccardia crassa. -The chiral title compounds (XVII) and (XIX) are synthesized from the chiral Michael addition product (VI) by combination of a Grignard reaction and an acid-catalyzed cyclization of