✦ LIBER ✦

Structure of [RhH2(PPh3)2(bipy)]Cl (bipy = 2,2′-bipyridyl) from multinuclear NMR studies

✍ Scribed by B. T. Heaton; C. Jacob; W. Heggie; P. R. Page; I. Villax

Publisher: John Wiley and Sons
Year: 1991
Tongue: English
Weight: 248 KB
Volume: 29
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260291307

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

By the use of the INEPT pulse sequence it has been possible to obtain ^15^N and ^103^Rh NMR data on [RhH~2~(PPh~3~)~2~(bipy)]Cl (bipy = 2,2′‐bipyridyl) containing natural abundance ^15^N and prove the stereochemistry; ^1^H and ^31^P NMR data are also reported for [RhH~2~(PPh~3~)~2~(bipy)]Cl which can be easily prepared in the pure state by the reaction of [RhCl(PPh~3~)~3~] or [Rh~2~Cl~2~(PPh~3~)~4~] with bipy ([Rh]: [bipy] = 1:1) under an H~2~ atmosphere.

📜 SIMILAR VOLUMES

NMR Study of L-Shaped (Quinoxaline)plati

NMR Study of L-Shaped (Quinoxaline)platinum(II) Complexes − Crystal Structure of [Pt(DMeDPQ)(bipy)](PF6)2

✍ Enrico Rotondo; Archimede Rotondo; Francesco Nicolò; Maria Letizia Di Pietro; Ma 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 183 KB

## Abstract A ^1^H and ^13^C NMR study of nine Pt^II^ complexes of DMeDPQ [6,7‐dimethyl‐2,3‐bis(2‐pyridyl)quinoxaline] and BDPQ [2,3‐bis(2‐pyridyl)benzo[__g__]quinoxaline], and the crystal structure of one of them, are reported. The results are consistent with __C__~__s__~ symmetry of “L‐shaped squ

NMR studies on the novel heterobimetalli

NMR studies on the novel heterobimetallic complexes [M(dppm)(Ph2PCH2PPh2PPPP) {Pt(PPh3)2}]OTf (M = Rh, Ir) derived from the stepwise activation of white phosphorus

✍ Maria Caporali; Pierluigi Barbaro; Sandra Bolaño; Luca Gonsalvi; Sonia Mañas Car 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 191 KB

Solid-state NMR study of [(Ph3SnF)2(Ph3S

Solid-state NMR study of [(Ph3SnF)2(Ph3SnO2PPh2)], a novel coordination polymer prepared from Bu4N[Ph3SnF2] and [Ph3SnOPPh2OSnPh3](O3SCF3)

✍ Jens Beckmann; Dainis Dakternieks; Andrew Duthie; Cassandra Mitchell; François R 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 170 KB 👁 1 views

Multinuclear High-Resolution NMR Study o

Multinuclear High-Resolution NMR Study of Compounds from the Ternary System NaF—CaF2—AlF3: From Determination to Modeling of NMR Parameters.

✍ C. Martineau; M. Body; C. Legein; G. Silly; J.-Y. Buzare; F. Fayon 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 11 KB 👁 1 views

Design of Tri-Substituted Dodecatungstos

Design of Tri-Substituted Dodecatungstosilicate from a Trilacunary Silicotungstate by Insertion of Manganese Ions of [Mn3(μ3-O)(2-Cl-benzoato)6(py)3]: Synthesis, Structure, Redox and Magnetic Studies

✍ Daipayan Dutta; Atish D. Jana; Mainak Debnath; Golam Mostafa; Rodolphe Clérac; J 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 498 KB 👁 1 views

Synthesis of Hydride Tantalabenzocyclope

Synthesis of Hydride Tantalabenzocyclopentene and µ-Alkylidene Complexes by Direct Alkylation Reactions of [TaCp*Cp′Cl2] − NMR Spectroscopic Study and X-ray Crystal Structure of [TaCp*Cp′(H)(η2-CH2-CMe2-o-C6H4)], (Cp* = η5-C5Me5; Cp′ = η5-C5H4SiMe3)

✍ Aurora Castro; Mikhail V. Galakhov; Manuel Gómez; Pilar Gómez-Sal; Avelino Martí 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 170 KB 👁 1 views