Structure of oxolucidine A, a lycopodium alkaloid
β Scribed by Motoo Tori; Tatsue Shimoji; Shigeru Takaoka; Katsuyuki Nakashima; Masakazu Sono; William A. Ayer
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 133 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
A Lycopodium alkaloid, oxolucidine A, was treated with NaBH 4 followed by p-bromobenzoyl chloride to afford a tribenzoate derivative, which was analyzed by X-ray crystallography to establish the stereostructure. The structure of lucidine A was also determined from these results except for the configuration at C-14.
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## Abstract A new alkaloid, miyoshianine C (**1**), was isolated from the whole plants of __Lycopodium japonicum__ Thunb., together with the known four compounds __Ξ±__βobscurine (**2**), lycodoline (**3**), miyoshianine A (**4**), and lucidioline (**5**). Their structures were elucidated on the bas