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Structure of NiII, PdII and PtII complexes with the bidentate ligand 2,11-bis(diethylphosphinomethyl)benzo[c]phenanthrene

✍ Scribed by Bachechi, F. ;Zambonelli, L.


Book ID
114508973
Publisher
International Union of Crystallography
Year
1992
Tongue
English
Weight
585 KB
Volume
48
Category
Article
ISSN
0108-2701

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The ligand 2,1 l-bis(diphenylphosphinomethyl)benzo[c]phenanthrene (1) has been used to prepare complexes of the type [PtL(l)] (L = C,H,, CH,=CH-CO,Me, PhC-CPh, MeC-CMe, MeO,CC=CCO,Me, (i-Pr)O,CC-CCO,(i-Pr), Ph,P and CO). It is shown that these complexes are less labile than the corresponding species

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Gradual decomposition occurs above the temperature stated. b, Recorded in CHCI, solution. ') Recorded in a nujol mull; shoulders at 2190 and 2100 are also observed. d, Recorded in a nulol mull.

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The structures of [RhCl(CO)(l)] and [PdC1,(1)], where 1 is the bidentate ligand (C6H5)2P . CH2 . ClsHlo . CH2 . P (C6H5),, have been determined from threedimensional X-ray counter data collected on single crystals of the C6H5. CN solvates. The two compounds are isomorphous and crystallize in the tri

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## Abstract The preparation of the ditertiary phosphines 2,11‐bis (di‐__m__‐tolylphosphinomethyl)benzo [__c__]phenanthrene (**1b**), 2,11‐bis (di‐__p__‐anisylphosphinomethyl)benzo‐[__c__]phenanthrene (**1c**), 2,11‐bis (di‐__m__‐trifluoromethylphenylphosphinomethyl) benzo‐[__c__]phenanthrene (**1d*