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Structure of new anionic conductors Bi4V2(1−xM2xO11−3x; M = Cu, Ni

✍ Scribed by M. Anne; M. Bacmann; E. Pernot; F. Abraham; G. Mairesse; P. Strobel


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
215 KB
Volume
180-181
Category
Article
ISSN
0921-4526

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Synthesis and Structure of [Sn4Se11]6–,
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Reaction of A 2 CO 3 (A = K, Rb) with Sn and Se in an H 2 O/CH 3 OH mixture at 115±130 °C affords the isotypic selenidostannates(IV) A 6 Sn 4 Se 11 ´x H 2 O (A = K, x = 8) 1 and 2 whose discrete [Sn 4 Se 11 ] 6± anions each contain two corner-bridged ditetrahedral [Sn 2 Se 6 ] 4± species. Similar re