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Bi2n+4MonO6(n+1) with n=3, 4, 5, 6: A new series of low-temperature stable phases in the mBi2O3 – MoO3 system (1.0<m<1.7): Structural relationships and conductor properties

✍ Scribed by Eladio Vila; Ángel R. Landa-Canovas; Jean Galy; Juan E. Iglesias; Alicia Castro


Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
893 KB
Volume
180
Category
Article
ISSN
0022-4596

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A novel three-dimensional hybrid solid, [{(Cu 4 I 4 ) 2 H 2 O}{Cu 6 (mtz) 6 }] n (1) (Hmtz = 3,5-dimethyl-1,2,4-triazole), was synthesized under solvothermal condition. The structure of 1 consists of four-connected Cu 4 I 4 clusters and hexanuclear Cu 6 (mtz) 6 rings as secondary building units (SBU