Racemic manganese(I1) (+)-1-malate t r i h y d r a t e c r y s t a l i z e s i n the space group Pcab, w i t h Z = 8 and a = 14.201(8), b = 14.656(4), c = 8.265(5)a. The Mn-ion i s surrounded by s i x oxygen atoms forming an octahedron, s l i g h t l y d i s t o r t e d by the r i g i d i t y o f o
β¦ LIBER β¦
Structure of manganese(II) (+)-malate trihydrate and comparison with other malates
β Scribed by Van Havere, W. ;Lenstra, A. T. H. ;Geise, H. J.
- Book ID
- 114527412
- Publisher
- International Union of Crystallography
- Year
- 1980
- Weight
- 320 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0567-7408
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## Abstract An exploration of the nickelβ malateβbpa system under hydrothermal conditions, has led to the isolation of a novel framework {[Ni(Hmal)(bpa)]Β·2.5H~2~O}~n~ (**1**) (Hmal = malate dianion, bpa = 1,2βbi(4βpyridyl)ethane). Singleβcrystal Xβray analyses reveal that it crystallizes in the ort