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Structure of La5Mo32O54 containing trans bicapped Mo8 octahedral clusters and tricluster Mo7–Mo10–Mo7 chain fragments

✍ Scribed by Gall, P. ;Toupet, L. ;Gougeon, P.


Book ID
114510148
Publisher
International Union of Crystallography
Year
1993
Tongue
English
Weight
595 KB
Volume
49
Category
Article
ISSN
0108-2701

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Synthesis, Structural Studies, and Physi
✍ J. Tortelier; P. Gall; H. Noël; P. Gougeon 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 240 KB

Polycrystalline samples and single crystals of the RE 5 Mo 32 O 54 compounds (R ‫؍‬ La, Ce, Pr, and Nd) were synthesized by solid state reactions at high temperature in sealed Mo crucibles. Their crystal structures were determined by single crystal X-ray diffraction methods. All four compounds are i