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Synthesis, structure and properties of Mn1.5Mo8O11, a unique structure type among compounds having infinite chains of Trans-Edge-Shared Octahedral Cluster Units

✍ Scribed by Clark D. Carlson; Lawrence F. Brough; Paul A. Edwards; Robert E. McCarley


Book ID
116017464
Publisher
Elsevier Science
Year
1989
Weight
995 KB
Volume
156
Category
Article
ISSN
0022-5088

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Polycrystalline samples and single crystals of the R 4 Mo 4 O 11 compounds (R ΒΌ Yb and Lu) were synthesized by solid-state reactions at high temperature in sealed Mo crucibles. The structure of Lu 4 Mo 4 O 11 (a ΒΌ 10.5611(1), b ΒΌ 5.61930(5), c ΒΌ 15.6877 (2), b ΒΌ 99.5131(4) and Z ΒΌ 4) was determined