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Structure of isopropyl 2-chloro-5-(2-methyl-1,4-oxathiin-3-ylcarbonylamino)benzoate, oxathiin carboxanilide

✍ Scribed by Silverton, J. V. ;Quinn, F. R. ;Haugwitz, R. D.


Book ID
114508363
Publisher
International Union of Crystallography
Year
1991
Tongue
English
Weight
342 KB
Volume
47
Category
Article
ISSN
0108-2701

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In the electron impact induced fragmentation of 2,3-disubstituted 5,6-dihydro-1,4-oxathiines, the cleavage of the heterocyclic ring proceeds through the retro Diels-Alder type of reaction. The further fragmentation of the resulting radical cation gives rise to substituted carbonyl or thiocarbonyl ca