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Structure of Ir4(CO)12 from its vibrational spectrum

✍ Scribed by F. Cariati; V. Valenti; G. Zerbi

Book ID
114041158
Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
480 KB
Volume
3
Category
Article
ISSN
0020-1693

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Solution Equilibria in Trialkyl-Phosphit
Solution Equilibria in Trialkyl-Phosphite Derivatives of [Ir4(CO)12]. Crystal Structure of [Ir4(CO)11{P(OCH2)3CEt}]
✍ Katya BesanΓ§on; GΓ‘bor Laurenczy; Tito Lumini; Raymond Roulet; Giuliana Gervasio πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 German βš– 576 KB

## Abstract The monosubstituted [Ir~4~(CO)~11~L] clusters (L = P(OPh)~3~, 1; L = P(OMe)~3~, 2; L = P(OCH~2~)~3~CEt, 3) were obtained in good yields by the reaction of [Ir~4~(CO)~11~I]^βˆ’^ with the corresponding phosphite. In the solid state, cluster 3 has a __C__~__s__~ geometry with all terminal li