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Crystal structure of tetrairidium dodecacarbonyl, Ir4(CO)12. An unpleasant case of disorder

✍ Scribed by Churchill, Melvyn Rowen; Hutchinson, John P.


Book ID
126177089
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
889 KB
Volume
17
Category
Article
ISSN
0020-1669

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Solution Equilibria in Trialkyl-Phosphit
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## Abstract The monosubstituted [Ir~4~(CO)~11~L] clusters (L = P(OPh)~3~, 1; L = P(OMe)~3~, 2; L = P(OCH~2~)~3~CEt, 3) were obtained in good yields by the reaction of [Ir~4~(CO)~11~I]^βˆ’^ with the corresponding phosphite. In the solid state, cluster 3 has a __C__~__s__~ geometry with all terminal li