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A tetrairidium cluster with a bridging SO2: The synthesis, fluxional behaviour, and crystal structure of Ir4(CO)9(μ2-CO)2(μ2-SO2)

✍ Scribed by Dario Braga; Renzo Ros; Raymond Roulet


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
312 KB
Volume
286
Category
Article
ISSN
0022-328X

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The Ditertiary-Phosphane-Bridged Heteron
✍ Yong Leng Kelvin Tan; Weng Kee Leong 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 271 KB

## Abstract A high‐yielding alternative synthesis of the dppm‐bridged heteronuclear cluster RuOs~3~(μ‐H)~2~(CO)~9~(μ‐CO)~2~(μ‐dppm) (1) [dppm = bis(diphenylphosphanyl)methane] has been developed. Thermolysis of 1 resulted in dephenylation of both phosphane groups to afford the butterfly cluster RuO