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Structure of di-μ-chloro-bis[trichlorobis(tetrahydrofuran)uranium(IV)]

✍ Scribed by Rebizant, J. ;Spirlet, M. R. ;Apostolidis, C. ;Van den Bossche, G. ;Kanellakopulos, B.


Book ID
114507977
Publisher
International Union of Crystallography
Year
1991
Tongue
English
Weight
335 KB
Volume
47
Category
Article
ISSN
0108-2701

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Di-μ-chloro-bis­[trichloro­(4-chloro­ani
✍ Wei, Hua ;Li, Ya-Hong ;Zhang, Yong 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 109 KB

The title compound, [Zr~2~Cl~8~(C~6~H~6~ClN)~2~], is centrosymmetric. Each Zr^IV^ ion has distorted octahedral coordination geometry, formed by one N atom from a 4-chloroaniline ligand, three terminal Cl^−^ ions and two bridging Cl^−^ ions. The Zr—μ-Cl bond distances are much longer than the other Z