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Structure of catena-poly-[{tetrakis-μ-(acetato-O:O')-dicopper(II)}-μ-{1,8-bis(3,5-dimethyl-1-pyrazolyl)-3,6-dithiaoctane-N2,N2'}]

✍ Scribed by Haanstra, W. G. ;Driessen, W. L. ;Reedijk, J. ;Wood, J. S.

Book ID
114509234
Publisher
International Union of Crystallography
Year
1992
Tongue
English
Weight
347 KB
Volume
48
Category
Article
ISSN
0108-2701

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✍ Dou, Qing-Qing ;He, Yong-Ke ;Zhang, Li-Tian ;Han, Zheng-Bo 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 667 KB

The title compound, {(C 10 H 10 N 2 )[Cu 2 (C 5 HN 2 O 4 ) 2 ]} n , has been synthesized under hydrothermal conditions. The self-assembly of the pyrazole-3,5-dicarboxylate ligands and Cu II atoms results in a one-dimensional anionic chain, in which the Cu II atom is five-coordinate in a square-pyram