The title compound, [Cu 2 (C 5 H 9 O 2 ) 4 (C 5 H 5 N) 2 ], consists of centrosymmetric binuclear cage units with four dimethylpropanoate bridges linking the two Cu centres [CuÁ Á ÁCu = 2.6229 (9) A ˚]. The square-pyramidal Cu coordination is completed by a pyridine N atom at the apical site. Astack
Structure of bis(benzenesulfonato-O)tetrakis(pyridine-N)copper(II)
✍ Scribed by Jedrzejas, M. J. ;Towns, R. L. R. ;Baker, R. J. ;Duraj, S. A. ;Hepp, A. F.
- Book ID
- 114509618
- Publisher
- International Union of Crystallography
- Year
- 1993
- Tongue
- English
- Weight
- 350 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.025 wR factor = 0.067 Data-to-parameter ratio = 15.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 275 K Mean '(C±C) = 0.005 A Ê R factor = 0.037 wR factor = 0.120 Data-to-parameter ratio = 18.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The Cu atom in the title compound, [Cu(C 5 H 11 NO 2 ) 4 ](PF 6 ) 2 , shows square-planar coordination. The asymmetric unit comprises one eighth of the molecular formula.