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Structure of an amorphous polymer electrolyte, poly(ethylene oxide)3:LiCF3SO3

✍ Scribed by Frech, Roger; Chintapalli, Sangamithra; Bruce, Peter G.; Vincent, Colin A.


Book ID
118151334
Publisher
Royal Society of Chemistry
Year
1997
Tongue
English
Weight
53 KB
Volume
2
Category
Article
ISSN
1359-7345

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Polymer electrolyte poly(ethylene oxide)
✍ JiΕ™Γ­ SpΔ›vÑček; JiΕ™Γ­ Dybal πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 100 KB πŸ‘ 1 views

Solid-state 13 C NMR spectra and ab initio calculations of 13 C NMR chemical shifts show that poly(ethylene oxide) (PEO) carbons in complex with LiCF 3 SO 3 (both in crystalline and amorphous phase) are more shielded in comparison with neat PEO, due to the coordination to the Li + cation. The result