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Poly(ethylene oxide) - LiCF3SO3 - polystyrene electrolyte systems

✍ Scribed by Fiona M. Gray; James R. MacCallum; Colin A. Vincent

Book ID: 104200306
Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 311 KB
Volume: 18-19
Category: Article
ISSN: 0167-2738
DOI: 10.1016/0167-2738(86)90127-x

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Solid-state 13 C NMR spectra and ab initio calculations of 13 C NMR chemical shifts show that poly(ethylene oxide) (PEO) carbons in complex with LiCF 3 SO 3 (both in crystalline and amorphous phase) are more shielded in comparison with neat PEO, due to the coordination to the Li + cation. The result