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Structure of a protected C(1)–C(10) subunit of erythronolides A and B

✍ Scribed by Lynch, V. M. ;Pacofsky, G. J. ;Martin, S. F. ;Davis, B. E.

Book ID
114506110
Publisher
International Union of Crystallography
Year
1989
Tongue
English
Weight
322 KB
Volume
45
Category
Article
ISSN
0108-2701

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The key synthons 2 and 3 [with suitable protecting groups] of the erythronolide A seco acid (1) have been prepared in an enantiomerically pure form, utilizing a stereoselective osmylation of chiral hydroxy (Z,E)-diene ester 6a and subsequent hydrogenation. Recent interest in macrolide and ionophore