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Structure of a Novel μ3-Oxo-FeCrIII-Glycine Complex

✍ Scribed by Dr. William Clegg; O. Mi Lam; Dr. Brian P. Straughan

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
237 KB
Volume
23
Category
Article
ISSN
0044-8249

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Formation and Structure of the Novel Heptanuclear Lead(II) Oxo Cluster [Pb7(μ3-O)(μ4-O)(μ3-OMe)4(μ2-I)4]I2 with an Unprecedented Cage Structure
✍ Yu-Jun Shi; Yan Xu; Xue-Tai Chen; Ziling Xue; Xiao-Zeng You 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 103 KB 👁 1 views

A novel lead(II) cluster [Pb 7 (µ 3 -O)(µ 4 -O)(µ 3 -OMe) 4 (µ 2 -I) 4 ]I 2 (1) has been isolated from the reaction mixture of PbI 2 and pyrazine in DMF/MeOH solvent with a reasonable yield (46%). The X-ray crystallography shows that 1 exhibits a novel unprecedented cage structure with centered µ 3