Molecules of the title compound, C 16 H 16 N 2 O 3 S, are linked by N-HÁ Á ÁS hydrogen bonds to form centrosymmetric dimers [NÁ Á ÁS = 3.4501 (13) A ˚]. The N 0 -phenyl and N-phenyl rings are twisted by 52.7 (1) and 23.3 (1) , respectively, from the essentially planar -NHC( S)NC( O)-moiety.
Structure of 4-methoxy-1-(N-phenyl)iminonaphthalene
✍ Scribed by Linden, A. ;Cameron, T. S. ;Hilborn, J. W.
- Book ID
- 114506239
- Publisher
- International Union of Crystallography
- Year
- 1989
- Tongue
- English
- Weight
- 476 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
In the title compound, C 27 H 23 N 3 O 5 , the pyrimidine ring is slightly puckered. The mean plane of the pyrimidine ring forms dihedral angles of 28.26 (10), 55.53 (9) and 55.96 (10) with the three benzene rings in the molecule. There are intramolecular and intermolecular C-HÁ Á ÁO interactions.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.043 wR factor = 0.126 Data-to-parameter ratio = 14.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.047 wR factor = 0.143 Data-to-parameter ratio = 9.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.