Structure of “3-ketolactose” [4-O-(β-D-xylo-hexopyranosyl-3-ulose)-D-glucopyranose] by 1H- and 13C-n.m.r. spectroscopy
✍ Scribed by André De Bruyn; Jozef Van Beeumen
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 310 KB
- Volume
- 228
- Category
- Article
- ISSN
- 0008-6215
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✦ Synopsis
After the oxidation of lactose by bacteria of the genus Agrobacterium'4, catalysed by the enzyme hexopyranoside cytochrome c oxidoreductase5, "3-ketolactose" [4-~-(B-D-xy~o-hexopyranosyl-3-ulose)-D-glucopyranose, l] was isolated from the cul-
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## Abstract The 1‐NH structure for 3‐azidoindazole has been demonstrated by the observation of ^1^H^1^H and ^13^C^1^H couplings involving the hydrogen atom attached to nitrogen. A comparison between 3‐azidoindazole and indazole shows that both compounds have the same tautomeric structure.
The structures of one tri-(1), two tetra-(2 and 3), and one hexa-saccharide (4) produced by treatment of barley flour, after removal of the starch components, with a fungal beta-D-glucanase (Finizyme) have been assigned on the basis of 1H- and 13C-n.m.r. data as follows: beta-D-Glcp-(1----3)-beta-D-