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Structural studies by 1H- and 13C-n.m.r. spectroscopy and circular dichroism of acetylated α- and β-d-gluco- and -manno-pyranosylarenes

✍ Scribed by Véronique Bellosta; Claude Chassagnard; Stanislas Czernecki


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
466 KB
Volume
219
Category
Article
ISSN
0008-6215

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The 13C-{1H}-n.m.r. spectra (acidic D,O, pD -1) of N-methyl-l-deoxynojirimycin (1,5-dideoxy-1,5-methyliminium-D-glucitol), an inhibitor of processing cx-D-glucosidases involved in glycopeptide biosynthesis, showed two isomers (-11:l ratio) differing in the stereochemistry of the N+DCH3 group. Assig