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Structure of 2,2-bis[3-(dimethylamino)propyl]-1,1,1,3,3,3-hexaphenyltristannane(2 Sn–Sn)

✍ Scribed by Schollmeyer, D. ;Hartung, H. ;Mreftani-Klaus, C. ;Jurkschat, K.


Book ID
114508564
Publisher
International Union of Crystallography
Year
1991
Tongue
English
Weight
344 KB
Volume
47
Category
Article
ISSN
0108-2701

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The dinuclear molecule of [(Me 3 SiCH 2 )Cl 2 Sn] 2 (CH 2 ) 3 adopts an extended conformation and features distorted tetrahedral tin centres, with the greatest distortion manifested in the CÐSnÐC angles of approximately 128 °. The distortions are ascribed to the influence of intermolecular SnÁÁÁCl i