Methyl 2-amino-2,6-dideoxy~-o-glucopyranoside-6-sulfonic acid (8) was prepared by oxidation of methyl 3,4-di-O-acety1-6-S-acetyl-2-benzamido-2-deo~-6-thio~-D-glu~p~anoside with hydrogen peroxide in acetic acid followed by N-and 0-deacylation with aqueous sodium hydroxide. Compound 8 was also obtaine
Structure of 2-amino-2,6-dideoxy-α-d-glucopyranose-6-sulfonic acid
✍ Scribed by Vega, R. ;López-Castro, A. ;Márquez, R.
- Book ID
- 114503618
- Publisher
- International Union of Crystallography
- Year
- 1986
- Tongue
- English
- Weight
- 310 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
The crystal and molecular structures of 2-amino-2-deoxy-a/fl-D-glucopyranose 3-sulfate (1) and 2-amino-2-deoxy-fl-D-glucopyranose 6-sulfate (2) have been determined by direct methods. The sugar rings have the expected 4C1 conformation and the geometries of the sulfate groups are comparable with thos
2-Amino-2,3-dideoxy-D-glucitol-3-sulfonic acid (3) and 2-amino-2,6-dideoxy-o-glucitol-6sulfonic acid (4) were prepared by reduction of 2-amino-2,3 (and 2,6)-dideoxy-D-glucopyranose-3 (and 6)-sulfonic acids with sodium borohydride. The crystal structure of 4 monohydrate (C6H15NOTS.H20) is orthorhombi