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Structural studies of O-sulfated D-glucosamines. The crystal and molecular structures of 2-amino-2-deoxy-α/ β-D-glucopyranose 3-sulfate (free acid) and 2-amino-2-deoxy-β-D-glucopyranose 6-sulfate (free base)

✍ Scribed by William Mackie; Edwin A. Yates; Doriano Lamba

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
473 KB
Volume
266
Category
Article
ISSN
0008-6215

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✦ Synopsis

The crystal and molecular structures of 2-amino-2-deoxy-a/fl-D-glucopyranose 3-sulfate (1) and 2-amino-2-deoxy-fl-D-glucopyranose 6-sulfate (2) have been determined by direct methods. The sugar rings have the expected 4C1 conformation and the geometries of the sulfate groups are comparable with those found in previous investigations except for a significant shortening of the C--O bond and closing of the C-<)-S bond angle in 2.

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