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Structure of (±)-(1R*,6S*)-1-benzyloxy-8,11,11-trimethyl-6-phenylthiobicyclo[5.3.1]undec-7-en-3-one

✍ Scribed by Lynch, V. M. ;Fishpaugh, J. R. ;Martin, S. F. ;Davis, B. E.


Book ID
114507797
Publisher
International Union of Crystallography
Year
1991
Tongue
English
Weight
322 KB
Volume
47
Category
Article
ISSN
0108-2701

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(−)-(1S,4S,6R,8R)-[11,11-Dimethyl-5-(4-t
✍ Ko, Kwang-Youn ;Yun, Hoseop 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 442 KB

The absolute configuration of the title compound, C 25 H 29 NO 4 S, has been determined unambiguously. The benzoyl group lies in an axial position and the oxazine ring adopts a chair conformation. One of the interesting features of this structure is that the carbonyl group is nearly perpendicular to