Structure of 1-benzyl(methyl)amino-1-deoxy-α-D-lyxo-hexulopyranose
✍ Scribed by Pérez, S. ;López-Castro, A. ;Márquez, R.
- Book ID
- 114525310
- Publisher
- International Union of Crystallography
- Year
- 1978
- Weight
- 375 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0567-7408
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The title tagatosamine, C 20 H 25 NO 5 .CH 4 O, formed in the Amadori rearrangement of d-galactose with dibenzylamine, is shown to crystallize as the -anomer, in contrast to theanomer formed in the Amadori reaction of d-glucose with dibenzylamine.
UDP-D-galactose:fl-D-galactopyranosyl-(l ~ 4)-2-acetamido-2-deoxy-D-glucose a-(1 ~ 3)-Dgalactopyranosyltransferase [E.C . 2.4.1.151] transfers o-galactosyl-residues from the sugar nucleotide with retention of configuration. We report here that synthetic methyl 3'-amino-3'-deoxy-N-acetyllactosaminide